Biking two-timer Jesse James will sit down for his first interview since splitting with soon-to-be ex-wife Sandra Bullock in a chat with Nightline, ABC News announced on Wednesday.

In March, James’ world came crashing down after his longtime mistress, Michelle “Bombshell” McGee, sold the story of their affair to In Touch Weekly for $30,000. The article set off a firestorm of controversy for the husband of the Oscar-winning actress, who was later romantically-linked to at least four other women during his five year marriage to Sandra.

After weeks of dodging the chorus of Americans screaming “Who would cheat on Sandra Bullock?,” the former reality TV star/suspected Nazi will finally give some insight into what happened in his marriage to America’s Sweetheart in a gut-wrenching discussion with ABC’s Vicki Mabrey. James is also expected to share the reason why he went to rehab and what role he’ll have in the life of Bullock’s infant son, Louis.

The interview will air Tuesday, May 25 at 11:35 PM.